Azobisisobutyronitrile (AIBN)

Azobisisobutyronitrile (AIBN)

CAS 78-67-1SolventsAIBN

Specifications

CAS No.
78-67-1
Melting point
107°C (decomposition)
Boiling point
Decomposes before boiling

Product overview

Azobisisobutyronitrile, commonly abbreviated as AIBN, is an organic compound with the formula [(CH3)2C(CN)]2N2. This white powder is soluble in organic solvents and is widely used as a radical initiator in polymer chemistry. AIBN decomposes at temperatures above 60°C, releasing nitrogen gas and generating two 2-cyanoprop-2-yl radicals that initiate polymerization reactions.

Key features

  • Efficient free radical initiator for polymerization
  • Decomposes smoothly at moderate temperatures (60-100°C)
  • Releases nitrogen gas during decomposition
  • Soluble in organic solvents (methanol, ethanol, ether, acetone)
  • Relatively safe compared to peroxide initiators
  • Produces consistent, predictable radical generation
  • Can be used in both aqueous and organic systems
  • Light-sensitive - should be stored in dark.

Applications

Polymer industry
initiator for vinyl polymerization (PVC, PS, PMMA, PAN)
Rubber production
initiator for emulsion and suspension polymerization
Foam plastics
blowing agent for foam rubber and plastics
Organic synthesis
radical reactions, Barton-McCombie deoxygenation
Adhesives and sealants
curing agent for acrylic adhesives
Coatings
initiator for UV-curable and thermal-cure coatings
Textile industry
polymer synthesis for fibers
Composite materials
curing initiator for resin systems
Research and development
standard initiator for kinetic studies.
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